Welcome Dr Sam Stranks, entrepreneur and professor at Cambridge University!
Perovskites0h 0m 49sThe family is based on the crystal structure0h 1m 15sHave been worked on for 2 to 3 decades0h 1m 44sOnly since 2009 have they been used as a solar cell0h 2m 36sSam's background is physicist0h 4m 46sRaised in Australia0h 6m 23sBroad undergrad background0h 7m 0sBridged chemistry and physics in Master's program0h 7m 22sWorked on removing white wine proteins0h 7m 32sThe mechanism is similar to how alzheimers blobs together0h 8m 50s20070h 10m 24sHe got a Rhodes scholarship which meant he ended up going to Cambridge University.0h 10m 29sResearch included carbon nanotubes0h 11m 7sWrapping polymes around then0h 11m 21sPopularity has been dropping0h 11m 47sFullerenes, Graphene both won Nobel prize.0h 12m 2sProducing nanotubes is difficult0h 12m 21sDave made a video about a bunkum Kickstarter doing Graphene heaters0h 12m 34sSpecifically separating out metallic and semiconductor types0h 12m 47sFinished PhD 20120h 15m 5sJoined Henry Snaith's group doing dye sensitized solar cells0h 15m 21sReemergence of perovskites0h 16m 21sThe initial focus was on a dye sensitive cell made out of perovskite0h 18m 25sEarly efficiency was 3%0h 18m 56sThe research is done in a place that looks more like a chemistry lab than a semi lab0h 22m 23sSolar simulator to replicate the sun0h 23m 40sHow are perovskites different from solar cells?0h 25m 34sSilicon has an indirect bandgap0h 26m 49sMultijunctions cells (the kind on satellites) have different absorbers (different colors)0h 27m 52sRecord silicon efficiency is 27%0h 28m 21sFull panel is about 20%0h 28m 39sPerovskite is at 23%0h 29m 5sTriple junction is 39%0h 29m 27sVideos from past guests Sam Zeloof and Jeri Ellsworth0h 30m 53sPrinted solar cells0h 32m 4sABX30h 34m 4sThickness only needs to be half a micron0h 34m 41sThe name 'perovskite solar cell' is derived from the ABX3 crystal structure of the absorber materials, which is referred to as perovskite structure. The most commonly studied perovskite absorber is methylammonium lead trihalide (CH3NH3PbX3, where X is a halogen atom such as iodine, bromine or chlorine), with an optical bandgap between 1.5 and 2.3 eV depending on halide content. Formamidinum lead trihalide (H2NCHNH2PbX3)0h 35m 56sCurrently using Indium for the contact, but it's hard to get, running out0h 36m 13sTalking through the stack0h 37m 12sBottom electrode is Indium Tin oxide0h 37m 37sThen a layer of perovskite0h 37m 53sTop layer is organic0h 38m 37sIllumnate through the glass,0h 39m 33sInSnOx is transparent up to UV0h 41m 14sPerovskite absorbs 200-8000h 41m 28sUsing lasers to test with pulses0h 44m 57sPulses for a 1 ps0h 45m 7sMonitor how they recombine and lose energy0h 45m 38sWhat causes a defect?0h 46m 23sWhat actually makes electrons mobile in the ABX3 structure?0h 49m 15sStructure is mostly from the B and the X (lead and iodide)0h 49m 35sCovalently bonding vs ionic bonding0h 52m 35sOther applications being targeted0h 56m 47sLight emission (LEDs)0h 56m 57sAlso using for lasing materials (LASERs)0h 59m 41sWant to make an electrically pumped laser0h 59m 55sHave been some changes in the A site that stabilize ion migration1h 1m 55sSam is a founder of Swift Solar1h 2m 29sThe 6 founders had spent time together in Henry Snaith's group1h 2m 43sFocusing on making tandem cells1h 3m 20sMaking a solar sheet1h 4m 13sMore solar cells in a smaller area1h 4m 59sPayback periods1h 5m 25sWhy hasn't this started on the production side yet?1h 6m 18sSolar is coming down to 20 cent per watt1h 6m 43sInstall costs are still $1 per watt1h 6m 56sThe lightweight aspects lowers the cost of installation1h 7m 20sSam did a TED talk1h 8m 13sIntegrated photovoltaics1h 8m 25sGroup web page1h 9m 27sWant to learn more about bandgaps? Check out pveducation.org1h 9m 33sScientific American wrote an article about The Perovskite Boom last year1h 9m 54sSam's lab is taking new students! Reach him via his web page or reach out to him on Twitter (@SamStranks)1h 11m 59sPhoto: Ryan Lash / TED