The present work combines palaeomagnetic and rock magnetic methods with clay mineralogy, isotope geochemistry of clay minerals and trace element geochemistry of Fe-oxide leachates to study remagnetised sedimentary rocks from Palaeozoic outcrops in Middle and Eastern Europe. Three areas were selected (NE Rhenish Massif, Barrandian and Holy Cross Mountains), where the causes of Late Palaeozoic remagnetisations are yet unclear. The results yield important implications for the processes and mechanisms responsible for the remagnetisations in the areas studied.
NE Rhenish Massif: A Late Carboniferous remagnetisation (component B) is identified in Late Palaeozoic carbonate and clastic rocks from the NE Rhenish Massif. Three individual incremental regional fold tests across the area show a unique and distinctive variation in timing of remagnetisation relative to the age of folding. The remagnetisation is postfolding in the South and of synfolding origin in the North of the area. Consequently, the timing and the duration of the remagnetisation event is constrained by the age of folding, which varies throughout the area and reflects a northward migration of the deformation front during 325 Ma to 300 Ma. Comparison of the resulting palaeolatitude of the NE Rhenish Massif with the palaeolatitudinal drift history for the region yields an estimate for the age of remagnetisation of ca. 315 - 300 Ma, which is in good agreement with the age of deformation. The concordance of the magnetic palaeoinclinations obtained from the entire area indicates that the rocks were remagnetised during a relatively short period of only a few My. The thermal stability of the remanence up to 550°C the comparably low palaeotemperatures in the studied region and the short duration of the remagnetisation event favour a chemical remagnetisation process.
Rock magnetic experiments reveal a complex magnetomineralogy of the remagnetised Palaeozoic sediments from the NE Rhenish Massif. The dominant carrier of the Carboniferous magnetisation component is magnetite, but pyrrhotite and hematite accompany magnetite as carrier of the NRM in some grey carbonates and red sandstones or red nodular limestones, respectively. The hysteresis ratios, magnetic viscosity and low temperature behaviour of the carbonate rocks give strong evidence for the presence of very fine grained (superparamagnetic) magnetic minerals. This material is also thought to be responsible for similar rock magnetic properties of siliciclastic rocks. This interpretation, however, is not unique for the siliciclastic rocks, due to the predominance of detrital MD magnetite and the high amount of paramagnetic material. The hysteresis ratios from medium to coarse grained rocks and reef carbonates fall in or close to the fields of MD magnetite and remagnetised carbonates, respectively. The fine grained clastic rocks (siltstones) and limestone turbidites have intermediate hysteresis properties. This implies the presence of very fine grained magnetic material in all lithologies of the NE Rhenish Massif, which is indicative for authigenic growth of magnetic minerals and formation of a CRM. However, the magnetic fingerprint of SP grains gets increasingly disguised with increasing amount of detrital MD magnetite in clastic rocks.
K-Ar dating of <0.2µm clay fractions indicates two diagenetic events in the NE Rhenish Massif. The observation of K-Ar isochrons rules out contamination from detrital sources and preferential loss of radiogenic ^40Ar from authigenic illites. Middle Devonian clastic rocks are characterised by an illitisation event at 336 +/- 6.2 Ma, which is probably connected to a major magmatic event at ca. 340 - 330 Ma in the Mid-German Crystalline Rise. The second period of illite formation at 312 +/- 10 Ma is coeval to the northward migration of deformation through the Rhenish Massif and is only recorded by Upper Devonian and Lower Carboniferous rocks. This indicates that the metamorphic conditions were n