Chemical Safety at Work - The Podcast

Ep.30: Spontaneously Combustible Substances: The Fire Risk You Didn't See Coming


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Some chemicals don’t need a flame to catch fire — just exposure to air. 

In this episode, Patrick Gee unpacks the hidden dangers of Class 4.2 spontaneously combustible substances — and what it takes to store and handle them safely. 

You’ll learn: 

  • The difference between pyrophoric and self-heating substances 
  • How Packing Groups classify danger levels 
  • The strict cabinet requirements under AS/NZS 5026 
  • What signage and ventilation systems are legally required 
  • Why training and risk assessments are non-negotiable 

Whether it’s white phosphorus or aluminium alkyls, this episode breaks down how to control one of the most underestimated fire risks in the workplace. 

🎧 Subscribe now to keep your dangerous goods knowledge sharp and your team safe. 

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Chemical Safety at Work - The PodcastBy Storemasta