In the second episode of Whiskey Web and Whatnot, Robbie Wagner and Charles W. Carpenter III try a Kentucky straight rye whiskey from Peerless Distilling. They discuss the pros and cons of monorepos, and talk about their favorite and least favorite Super Bowl commercials. They also chat about the challenges of coordinating while living on opposite sides of the country and joke about their different whiskey preferences. Overall, the episode is a fun and lighthearted exploration of whiskey tasting with some humorous banter thrown in.