Venus’ mass and radius are similar to those of Earth, yet its internal structure, chemical composition, and overral evolution and dynamics remain poorly constrained. A striking difference is Venus’ exceptionally long lava flows, for example observed by NASA’s Magellan mission, which may play a critical role in shaping its evolution and surface tectonics. Small deviations from Earth-like properties could explain the different geological and atmospheric histories of the two planets. We investigate the influence of possible bulk compositions and internal structures on Venus’ thermal and compositional evolution. Using ten models from Shah et al. (2022) that range from a small to a big, and from a S-free to a S-rich core, we perform mantle convection simulations with the code StagYY (Tackley, 2008). Different tectonic scenarios are explored, including stagnant lid, episodic lid, and plutonic-squishy lid regimes. Variations in core size and composition significantly affect mantle melting, heat flow, lithospheric temperature, and observables such as moment of inertia and Love numbers. To capture the role of volcanism, we extend StagYY to incorporate lateral lava spreading, a process not considered in previous global models. We examine how spreading angles impact crustal thickness, mantle temperature, eruption rates, heat flow, and atmospheric outgassing. Our results suggest that lava flows can significantly modify Venus’ tectonic style. Our models produce a range of predictions that can be compared to observations by planned missions to Venus, including EnVision measurements by the VenSpec spectrometers, comprising outgassing of water and other volatiles and surface composition. These can be used to constrain Venus’ interior composition and structure, and reveal key information on the differences between Earth and Venus.