Uranium-235 is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, it can sustain a fission chain reaction. It is the only fissile isotope that is a primordial nuclide or found in significant quantity in nature. Plutonium-239 is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 has also been used. Plutonium-239 is also one of the three main isotopes demonstrated usable as fuel in thermal spectrum nuclear reactors, along with uranium-235 and uranium-233. Plutonium-239 has a half-life of 24,110 years.

There were still many unknown factors. The properties of pure uranium-235 were relatively unknown, as were those of plutonium, an element that had only been discovered in February 1941 by Glenn Seaborg and his team. The scientists at the Berkeley conference envisioned creating plutonium in nuclear reactors where uranium-238 atoms absorbed neutrons that had been emitted from fissioning uranium-235 atoms. At this point no reactor had been built, and only tiny quantities of plutonium were available from cyclotrons. Even by December 1943, only two milligrams had been produced. There were many ways of arranging the fissile material into a critical mass. The simplest was shooting a "cylindrical plug" into a sphere of "active material" with a "tamper"—dense material that would focus neutrons inward and keep the reacting mass together to increase its efficiency. They also explored designs involving spheroids, a primitive form of "implosion" suggested by Richard C. Tolman, and the possibility of autocatalytic methods, which would increase the efficiency of the bomb as it exploded.

Considering the idea of the fission bomb theoretically settled—at least until more experimental data was available—the Berkeley conference then turned in a different direction. Edward Teller pushed for discussion of a more powerful bomb: the "super", now usually referred to as a "hydrogen bomb", which would use the explosive force of a detonating fission bomb to ignite a nuclear fusion reaction in deuterium and tritium. Teller proposed scheme after scheme, but Bethe refused each one. The fusion idea was put aside to concentrate on producing fission bombs. Teller also raised the speculative possibility that an atomic bomb might "ignite" the atmosphere because of a hypothetical fusion reaction of nitrogen nuclei Bethe calculated that it could not happen, and a report co-authored by Teller showed that "no self-propagating chain of nuclear reactions is likely to be started." In Serber's account, Oppenheimer mentioned it to Arthur Compton, who "didn't have enough sense to shut up about it. It somehow got into a document that went to Washington" and was "never laid to rest".

Information Link

https://en.wikipedia.org/wiki/Manhattan_Project