Pop sensation Justin Timberlake and actress Jessica Biel make a gorgeous couple, but how did they get “NSYNC” with their relationship? Find out how the two met, fell in love, broke up in 2011, and eventually got married in this episode of “Hooked Up to Hitched.” Hosts Eileen Reslen and Brian Faas bring you all the romantic details, including the Timberlakes’ secret wedding in southern Italy.

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