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The hydrogen economy is an important new growth area for platinum group metals (PGMs) and, in turn, PGMs are pivotal for hydrogen production and application across a broad front.
Accentuating this in a Zoom interview with Mining Weekly, Heraeus Precious Metals new business development executive VP Dr Philipp Walter highlighted the strong global current momentum of the hydrogen economy - "politically, socially and technologically". (Also watch attached Creamer Media video.)
"There'll be significant growth," Walter forecast shortly before departing for Asia to visit customers.
To meet that growth, Heraeus Precious Metals has formed its new Business Line Hydrogen Systems unit to focus on hydrogen applications, in particular proton exchange membrane (PEM) electrolysis and fuel cells, as well as the recycling of spent electrolysers and membranes.
"When I started in this role five years ago, now and then there was an article about hydrogen and PEM electrolysis, but nowadays, these are skyrocketing," he noted.
Amid the need to replace the anticipated potential loss of PGM demand to battery electric vehicles, hydrogen is seen as providing abundant opportunity to replace expected PGM demand loss - and then some. (Also see attached infographics.)
The hydrogen-related applications in which PGMs play a key role may begin with green hydrogen using PEM electrolysis but they certainly do not end there, extending as they do to other elements in PEM electrolysers, and so much more beyond that.
PGMs, for example, are again key in the transport of hydrogen through carriers such as liquid organic hydrogen carriers or LOHC, ammonia, methanol and fuel cells. The European Clean Hydrogen Alliance has just published the Learnbook on hydrogen imports into the EU market, citing LOHC technology as a viable hydrogen transport solution. LOHC can use existing non-cryogenic liquid fuel infrastructure at ports, thus transforming assets without leaving stranded investments.
Green hydrogen depends on especially PEM electrolysis technology owing to this coping best with renewable energy fluctuations.
In addition, platinum, iridium and now also ruthenium play electrocatalytic roles in splitting water into hydrogen and oxygen, with PGMs also being used as catalysts to crack ammonia into nitrogen and hydrogen and to convert carbon dioxide into methanol or other hydrogen-carrier molecules.
Furthermore, PGM catalysts are essential in gas purification through palladium membranes, by either removing oxygen in a hydrogen stream or removing hydrogen in an oxygen stream.
In fuel cells, platinum on carbon catalysts are used to generate energy out of hydrogen and oxygen, forming water.
When hydrogen is converted into electricity by fuel cells, platinum allows the energy to be released in a controlled manner as mobile and stationary power, which is so useful in areas not served by national electricity grids.
The essential need to have enough Iridium available to accommodate and accompany PEM electrolysis growth is already being met by highly successful thrifting achievements as well as through the addition of ruthenium.
This not only reduces reliance on iridium, a highly scarce and expensive PGM, but also reduces material cost.
Primary production of ruthenium, also a PGM, is three-and-a-half times greater than the primary production of iridium.
While some are seeking to substitute PGMs completely, being able to do so is seen as being highly unlikely.
"As a chemist, I find that difficult because I believe platinum group metals and hydrogen belong together, simply because of their chemical nature," was Walter's comment to Mining Weekly on the issue of substitution.
"Everybody dealing with platinum group metals also knows that thrifting is part of the DNA of platinum group metals," he added.
Significant thrifting has not only been achieved with environmental catalysts, but also with autocatalyst...