Twentyfirst Arnold Sommerfeld Lecture Series, Advances in light sources and time resolved spectroscopy have made it
possible to excite specific atomic vibrations in solids and to observe the
resulting changes in electronic properties. I argue that in narrow-band
systems the dominant symmetry-allowed coupling between electron density
and dipole active modes implies an electron density-dependent squeezing of
the phonon state which provides an attractive contribution to the electron-electron
interaction, independent of the sign of the bare electron-phonon
coupling and with a magnitude proportional to the degree of laser-induced
phonon excitation. Reasonable excitation amplitudes lead to non-negligible
attractive interactions that may cause significant transient changes in
electronic properties including superconductivity. The mechanism is
generically applicable to a wide range of systems, offering a promising route
to manipulating and controlling electronic phase behavior in novel materials.