Anakin Showed up in Episode 3 with a scar just to the corner of his right eye, something reminiscent to Scar in the Lion King. I suppose Lucas' point of putting it there was to symbolize his growth from the boy we saw in attack of the clones to a hardened and much more mature Anakin Skywalker in Revenge of the Sith. This podcast explains how he got his scar from Asajj Ventress.

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