We discuss the history of finding quasicrystals, those arrays of atoms that are like crystals--but aren't quite crystals. These are rarely talked about in undergraduate classes. We start with a purely mathematical question by David Hilbert, and move forward through the 1960s and 1970s, till actual quasicrystals were discovered in the 1980s. Then we reach the point where natural quasicrystals were found. Then we hear about some of their potential uses.

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We finally return to polymers, but in a more ecological way. We learn about using wood waste to make plastics. We hear of how to make plastic naturally degrade in the environment, whether with bacteria, sunlight, zapping it with ions, or heating up without oxygen. We also learn of new methods to mine plastics for hydrogen as fuel.

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• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We give a "solid foundation" to chemistry by recounting the history of concrete, starting with the earliest architectural use of lime around 10,000 years ago. We continue through ancient history and modern times with Roman concrete, the loss of its recipe, and (partial) rediscovery in the Renaissance. We continue to the present and the likely complete rediscovery of Roman concrete in the 21st century. We talk of the chemical reactions to make and set concrete, and its ecological problems. Finally we learn a bit about some efforts to make concrete a little more "green."

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• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

This episode relates the history of the new field of "skeletal editing" of molecules. While there have been a few known reactions of this type since the very late 1800s, the general system was unknown till the 21st century, beginning with Marcos Suero. We add to the mix Mark Levin and Guangbin Dong, talk of what precisely this type of chemistry does, and relate the wish-list of chemists of all the wonderful things that scientists would like in skeletal editing.

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• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

We reach the Big 1-5-0, in which I discuss the venerable history of mRNA vaccines, from the 1960s to the present, from a chemical point of view. We hear of transferring mRNA into cells, then transferring anti-viral mRNA into cells. There are a variety of mRNA vaccines under study--not merely COVID, but flu, RSV, and even cancer treatments. Patreon supporters may download a supplemental sheet with diagrams of some of the biochemical systems I describe.

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• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In this episode we touch on how chemistry has directly influenced religion. Our example is how knowledge of chemistry affected a rabbi's decision to allow a certain brand of carbonated beverage to claim that it is kosher, that is, fit to be ingested by Jews who follow traditional Jewish laws and customs regarding food.

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• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

What if we could make flexible electronics for clothing or medical sensors? We examine the history of this quest from the 1990s onward, focusing on liquid-metal electronics. We explore what that means, the pros and cons, and how it might work. Then we talk about creating electronic components using wood (really!), which began in the 2010s, ranging from wooden batteries to wooden transistors.

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• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

The history of chemistry in water microdroplets is discussed. We start with the observation by R. Graham Cooks that certain chemical reactions went faster inside ultra-small droplets of liquid relative to beaker-sized amounts. We examine the years-long arguments between Dick Zare and Himanshu Mishra over peroxide formation in microdroplets. We talk a bit about some reasons why reactions may go differently in tiny drops versus bulk amounts, and counter-arguments.

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• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In this episode we examine the history of non-lithium batteries. We talk of changing the anode material and cathode material, whether separately or together. This involves changing the graphite anode to silicon, changing to sulfur anodes, air-based cathodes, different solvent molecules to assist transport of lithium ions, and even calcium batteries. Finally we discuss the flow battery, invented way back in the 19th century, but being revived for batteries that can be stationary.

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• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook

In which we learn about the beginnings of chemistry applied to art conservation, from the initial attempts by Edward Forbes, but especially when he hired Rutherford John Gettens. We discuss Harvard University's Pigment Collection, plus various analytical tools chemists use to examine art, both light-based and non-light-based. We talk of several institutions with strong chemical applications for art conservation. Finally we examine the problems of modern products--polymers--that need to be preserved, from toys to photographic film.

Support the show

• Support my podcast at https://www.patreon.com/thehistoryofchemistry
• Tell me how your life relates to chemistry! E-mail me at [email protected]
• Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook